Функциональные мономеры

N,N-Диметиламиноэтилметакрилат (DMAEMA)

N,N-Dimethylaminoethyl Methacrylate, commonly known as DMAEMA (CAS 2867-47-2), is a versatile and high-purity functional monomer belonging to the amino-methacrylate family. It is characterized by the presence of a tertiary amine group and a polymerizable methacrylate moiety, making it an essential building block for advanced specialty polymers. In the global chemical market, DMAEMA serves as a critical intermediate for synthesizing cationic polymers through direct polymerization or subsequent quaternization reactions. Its dual functionality allows for the introduction of both hydrophilic and reactive sites into polymer backbones, enhancing properties like adhesion, solubility, and electrostatic interaction. As a clear, low-viscosity liquid, DMAEMA is prized for its excellent reactivity in free-radical polymerization processes. It plays a pivotal role in diverse sectors, ranging from water treatment and coatings to personal care and pharmaceuticals, where it facilitates the creation of high-performance flocculants, dispersants, and conditioning agents.

Характеристики

Ключевые свойства и преимущества

  • Superior Reactivity: Readily undergoes free-radical polymerization for efficient processing.
  • Dual Functionality: Offers tertiary amine and acrylic functionality for versatile chemical modifications.
  • Enhanced Adhesion: Improves bonding on various substrates in coating and adhesive formulations.
  • Water Solubilization: Provides pH-dependent solubility and cationic character upon neutralization or quaternization.
  • High Purity Standards: Rigorous quality control ensures low impurity levels, minimizing side reactions and color formation in final products.
  • Improved Dispersion: Acts as an effective stabilizer and dispersant in complex aqueous systems.
  • UV Resistance: Contributes to the durability and weatherability of finished polymer films.
Спецификации

Технические особенности

  • Chemical State: Clear, colorless to pale yellow liquid with a characteristic amine odor.
  • Boiling Point: Approximately 182-192°C at 760 mmHg.
  • Specific Gravity: Ranges from 0.930 to 0.935 at 20°C.
  • Solubility: Miscible with water and most organic solvents including alcohols, ethers, and hydrocarbons.
  • Stabilization: Typically stabilized with MEHQ (Hydroquinone monomethyl ether) to prevent premature polymerization.
  • Handling: Store in cool, dry conditions away from heat and direct sunlight; use stainless steel or polyethylene containers.
  • Safety: Classified as a corrosive and sensitizing material, requiring appropriate personal protective equipment and ventilation.

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Практическое применение в отраслях

Области применения

  • Water Treatment: Synthesis of high-molecular-weight cationic flocculants and coagulants for wastewater processing.
  • Personal Care: Essential in hair fixatives, conditioners, and antistatic agents for cosmetic formulations.
  • Coatings and Adhesives: Used as an adhesion promoter and crosslinking monomer in automotive and industrial finishes.
  • Paper Industry: Enhances retention and drainage aids, improving paper strength and quality.
  • Oil Field Chemicals: Utilized in the production of scale inhibitors and enhanced oil recovery agents.
  • Textiles: Employed in the manufacturing of fabric softeners and dye-fixing agents.
  • Pharmaceuticals: Serves as an intermediate for specialty medical polymers and drug delivery systems.
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